All stereoisomers of â-methoxytyrosine (â-OMeTyr), a stereo-undefined component of callipeltin A, were synthesized from L- and D-tyrosine. The stereochemistry of â-OMeTyr in callipeltin A was determined to be 2R,3R by an oxidative procedure and Marfey’s analysis.
Concise Synthesis of All Stereoisomers of b-Methoxytyrosine and Determination of the Absolute Configuration of the Residue in Callipeltin A
CASAPULLO, Agostino;MONTI, Maria Chiara;
2005-01-01
Abstract
All stereoisomers of â-methoxytyrosine (â-OMeTyr), a stereo-undefined component of callipeltin A, were synthesized from L- and D-tyrosine. The stereochemistry of â-OMeTyr in callipeltin A was determined to be 2R,3R by an oxidative procedure and Marfey’s analysis.File in questo prodotto:
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