Enantiomerically enriched beta-keto sulfoxides are obtainable by an alternative method to the classical reaction of the enantiomerically pure alpha-sulfinyl anion with esters or by Andersen's synthesis, through Sharpless modified kinetic resolution of racemic beta-keto sulfoxides. High e.e.s are achieved by combining asymmetric oxidation and kinetic resolution using furylhydroperoxides as oxidants

Alternative approach for the synthesis of chiral b-keto sulfoxides by furylhydroperoxides enantioselective oxidations

LATTANZI, Alessandra;SCETTRI, Arrigo
1998-01-01

Abstract

Enantiomerically enriched beta-keto sulfoxides are obtainable by an alternative method to the classical reaction of the enantiomerically pure alpha-sulfinyl anion with esters or by Andersen's synthesis, through Sharpless modified kinetic resolution of racemic beta-keto sulfoxides. High e.e.s are achieved by combining asymmetric oxidation and kinetic resolution using furylhydroperoxides as oxidants
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11386/1060523
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 20
  • ???jsp.display-item.citation.isi??? 17
social impact