In this work a series of co-polyamides were prepared by random polymerization of ε-caprolactam in presence of four different co-monomers at a percentage of 5% w/w, with the aim of verifying their suitability as film-forming materials. The effects of structural changes induced in the ε-caprolactam homopolymer by co-monomers were evaluated in both molten and solid states. Rheological tests in shear and elongational flow were performed to evaluate the processability of co-polyamides. Cast films were obtained and their thermal, mechanical and transport properties were evaluated to establish the performances of the co-polyamides in view of packaging applications. The results indicate that co-polyamide films having a partially aromatic structure display the best mechanical performances and show a significant improvement in barrier properties to gases compared to the homopolymer.
Influence of co-monomer structure on properties of co-polyamide packaging films
SCARFATO, Paola;DI MAIO, Luciano;INCARNATO, Loredana;
2002-01-01
Abstract
In this work a series of co-polyamides were prepared by random polymerization of ε-caprolactam in presence of four different co-monomers at a percentage of 5% w/w, with the aim of verifying their suitability as film-forming materials. The effects of structural changes induced in the ε-caprolactam homopolymer by co-monomers were evaluated in both molten and solid states. Rheological tests in shear and elongational flow were performed to evaluate the processability of co-polyamides. Cast films were obtained and their thermal, mechanical and transport properties were evaluated to establish the performances of the co-polyamides in view of packaging applications. The results indicate that co-polyamide films having a partially aromatic structure display the best mechanical performances and show a significant improvement in barrier properties to gases compared to the homopolymer.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
