In the title compound, [Ni(C24H36P3)Cl], the NiII atom adopts a distorted square-planar geometry with the two neutral P atoms of the tridentate ligand trans to one another. Bond lengths and angles of the phosphide P atom feature a pyramidal geometry of the donor atom, which forms a single bond with the NiII atom, retaining a stereochemically active lone pair.
Bis{bis[2-(diisopropylphosphanyl)phenyl]phosphanido- k3P,P 'P ''}chloridonickel(II)
TEDESCO, Consiglia;LAMBERTI, Marina;MAZZEO, Mina
2012-01-01
Abstract
In the title compound, [Ni(C24H36P3)Cl], the NiII atom adopts a distorted square-planar geometry with the two neutral P atoms of the tridentate ligand trans to one another. Bond lengths and angles of the phosphide P atom feature a pyramidal geometry of the donor atom, which forms a single bond with the NiII atom, retaining a stereochemically active lone pair.File in questo prodotto:
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