The title dinuclear compound, bis[-6,6'-di-tert-butyl-4,4'-dimethyl-2,2-(ethylenedithio)diphenolato]bis[methylaluminium(I)], [Al2(CH3)2(C24H32O2S2)] or [AlMe(etbmp)]2 [where etbmpH2 is 6,6'-di-tert-butyl-4,4'-dimethyl-2,2- (ethylenedithio)diphenol], was obtained by reaction of trimethylaluminum with etbmpH2, as shown by X-ray diffraction of a single crystal. The molecule possesses a crystallographic twofold axis.
A dimeric alkyl complex supported by an O,S,S,O-tetradentate diphenolate ligand
OLIVA L.;
2005
Abstract
The title dinuclear compound, bis[-6,6'-di-tert-butyl-4,4'-dimethyl-2,2-(ethylenedithio)diphenolato]bis[methylaluminium(I)], [Al2(CH3)2(C24H32O2S2)] or [AlMe(etbmp)]2 [where etbmpH2 is 6,6'-di-tert-butyl-4,4'-dimethyl-2,2- (ethylenedithio)diphenol], was obtained by reaction of trimethylaluminum with etbmpH2, as shown by X-ray diffraction of a single crystal. The molecule possesses a crystallographic twofold axis.File in questo prodotto:
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