The reactivity of commercially available or easily accessible hydroperoxides has been conveniently exploited for the achievement of highly efficient and enantioselective catalytic modifications of Modenas protocol for the asymmetric oxidation of sulfides. A notably enhanced enantioselectivity has been obtained by exploiting a concomitant process of stereoconvergent kinetic resolution taking place under catalytic conditions.

A re-investigation of Modena’s protocol for the asymmetric oxidation of prochiral sulfides

MASSA, Antonio;SCETTRI, Arrigo
2005

Abstract

The reactivity of commercially available or easily accessible hydroperoxides has been conveniently exploited for the achievement of highly efficient and enantioselective catalytic modifications of Modenas protocol for the asymmetric oxidation of sulfides. A notably enhanced enantioselectivity has been obtained by exploiting a concomitant process of stereoconvergent kinetic resolution taking place under catalytic conditions.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11386/1049213
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