Enantioselective preparation of 1(R)-hydroxypolygodial (5) has been achieved starting from alpha-ionone through a synthetic strategy involving a Corey-Bakshi-Shibata oxazaborolidine-mediated reduction and a stereoselective Diels-Alder reaction as key steps.
Enantioselective synthesis of 1 (R)-hydroxypolygodial
DELLA MONICA, Carmela;DELLA SALA, Giorgio;IZZO, Irene;SPINELLA, Aldo
2005
Abstract
Enantioselective preparation of 1(R)-hydroxypolygodial (5) has been achieved starting from alpha-ionone through a synthetic strategy involving a Corey-Bakshi-Shibata oxazaborolidine-mediated reduction and a stereoselective Diels-Alder reaction as key steps.File in questo prodotto:
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