Two different bridges were introduced at the 1,5:3,7-positions of p-tert-butycalix[8]arene I using a two-step alkylation procedure. A probable cation template effect in the introduction of the second bridge was evidenced. The obtained bis-bridged derivatives 3 possess encapsulating properties toward alkali cations modulated by the length and nature of the bridges.
Synthesis and complexing properties of 1,5:3,7-doubly bridged calix[8]arenes with mixed spanning elements
GAETA, CARMINE;NERI, Placido
2004
Abstract
Two different bridges were introduced at the 1,5:3,7-positions of p-tert-butycalix[8]arene I using a two-step alkylation procedure. A probable cation template effect in the introduction of the second bridge was evidenced. The obtained bis-bridged derivatives 3 possess encapsulating properties toward alkali cations modulated by the length and nature of the bridges.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
