Allylic alcohols undergo an efficient process of diastereoselective epoxidation by t-butyl hydroperoxide (TBHP) in n-hexane solution in the presence of catalytic amounts of mono- and bis-cyclopentadienyl titanium(IV) and zirconium(IV) chlorides.
Metallocene-catalyzed diastereoselective epoxidation of allylic alcols
DELLA SALA, Giorgio;LATTANZI, Alessandra;PROTO, Antonio;SCETTRI, Arrigo
2000
Abstract
Allylic alcohols undergo an efficient process of diastereoselective epoxidation by t-butyl hydroperoxide (TBHP) in n-hexane solution in the presence of catalytic amounts of mono- and bis-cyclopentadienyl titanium(IV) and zirconium(IV) chlorides.File in questo prodotto:
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