Mo(CO)(6)/t-butyl hydroperoxide, well known to epoxidize olefins, was shown to be a mild and very efficient system for the autoxidation of 5-alkylidene-4,5-dihydrofurans. High yields of primary, secondary and tertiary furyl hydroperoxides have been achieved employing catalytic amount of Mo(CO)(6). A radical mechanism is in agreement with the experimental data.
Mo(CO)6/TBHP catalyzed autoxidation of 5-alkylidene-4,5-dihydrofurans
LATTANZI, Alessandra;IANNECE, Patrizia;
1999
Abstract
Mo(CO)(6)/t-butyl hydroperoxide, well known to epoxidize olefins, was shown to be a mild and very efficient system for the autoxidation of 5-alkylidene-4,5-dihydrofurans. High yields of primary, secondary and tertiary furyl hydroperoxides have been achieved employing catalytic amount of Mo(CO)(6). A radical mechanism is in agreement with the experimental data.File in questo prodotto:
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