Mo(CO)(6)/t-butyl hydroperoxide, well known to epoxidize olefins, was shown to be a mild and very efficient system for the autoxidation of 5-alkylidene-4,5-dihydrofurans. High yields of primary, secondary and tertiary furyl hydroperoxides have been achieved employing catalytic amount of Mo(CO)(6). A radical mechanism is in agreement with the experimental data.

Mo(CO)6/TBHP catalyzed autoxidation of 5-alkylidene-4,5-dihydrofurans

LATTANZI, Alessandra;IANNECE, Patrizia;
1999

Abstract

Mo(CO)(6)/t-butyl hydroperoxide, well known to epoxidize olefins, was shown to be a mild and very efficient system for the autoxidation of 5-alkylidene-4,5-dihydrofurans. High yields of primary, secondary and tertiary furyl hydroperoxides have been achieved employing catalytic amount of Mo(CO)(6). A radical mechanism is in agreement with the experimental data.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11386/1060522
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