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EnglishQuinoline-based homo- and copolymers have been synthesized by the acid-catalyzed Friedlaender condensation between bis(o-aminoketone)s and silicon-containing bis(ketomethylene) monomers. The polymers contain quaternary silicon atoms and are fully aromatic; they show improved solubility compared to known polyquinolines with approximately unchanged softening and decomposition temperatures of the final material. A new solubilization method was developed for these materials. In addition two block copolymers based on an aramid block containing fluorene cardo units and polyquinoline were prepared.
http://hdl.handle.net/11386/1129046| Titolo: | Processable Fully Aromatic Quinoline-based Polymers |
| Autori interni: | CONCILIO, Simona |
| Data di pubblicazione: | 2001 |
| Rivista: | MACROMOLECULES |
| Abstract: | Quinoline-based homo- and copolymers have been synthesized by the acid-catalyzed Friedlaender condensation between bis(o-aminoketone)s and silicon-containing bis(ketomethylene) monomers. The polymers contain quaternary silicon atoms and are fully aromatic; they show improved solubility compared to known polyquinolines with approximately unchanged softening and decomposition temperatures of the final material. A new solubilization method was developed for these materials. In addition two block copolymers based on an aramid block containing fluorene cardo units and polyquinoline were prepared. |
| Handle: | http://hdl.handle.net/11386/1129046 |
| Appare nelle tipologie: | 1.1.2 Articolo su rivista con ISSN |
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