Thioureas straightforwardly derived from commercially available enantiopure amino alcohols have been found to promote the asymmetric Morita-Baylis-Hillman reaction of 2-cyclohexen-1-one and different aldehydes in the presence of triethylamine under solvent-free conditions. The corresponding allylic alcohols were obtained in good to high yields and up to 88% ee.

Asymmetric Morita-Baylis-Hillman reaction catalyzed by simple amino alcohol-derived thioureas

LATTANZI, Alessandra
2007-01-01

Abstract

Thioureas straightforwardly derived from commercially available enantiopure amino alcohols have been found to promote the asymmetric Morita-Baylis-Hillman reaction of 2-cyclohexen-1-one and different aldehydes in the presence of triethylamine under solvent-free conditions. The corresponding allylic alcohols were obtained in good to high yields and up to 88% ee.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11386/1741861
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