Starting from easily available (+)-norcamphor and according to an established approach, the 2-benzo[b]furyl hydroperoxide exo-5 was obtained in 58% overall yield. In order to ascertain the impact of the modification on the activity of this chiral oxidant, a study was carried out employing it in the asymmetric epoxidation of an allylic alcohol and alpha,beta-enones.
Synthesis of a benzo[b]furyl (+)-Norcamphor-derived hydroperoxide: study of the activity as an oxidant in asymmetric epoxidations
LATTANZI, Alessandra;SCETTRI, Arrigo
2008
Abstract
Starting from easily available (+)-norcamphor and according to an established approach, the 2-benzo[b]furyl hydroperoxide exo-5 was obtained in 58% overall yield. In order to ascertain the impact of the modification on the activity of this chiral oxidant, a study was carried out employing it in the asymmetric epoxidation of an allylic alcohol and alpha,beta-enones.File in questo prodotto:
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