A novel dimeric (x-diimine iron(II) complex, [(dab)FeCl-(mu-Cl)](2) (dab = 1,4-bis-cyclohexyl-1,4-diazabutadiene) was synthesized and structurally characterized by single crystal X-ray diffraction and VT H-1 NMR spectroscopy. The performances of this complex in atom transfer radical polymerization (ATRP) of styrene have been studied and related to the molecular structure.
Synthesis, characterization and role of a novel dimeric a-diimine iron (II) complex in ATRP of styrene
MILIONE, Stefano;GRASSI, Alfonso
2008
Abstract
A novel dimeric (x-diimine iron(II) complex, [(dab)FeCl-(mu-Cl)](2) (dab = 1,4-bis-cyclohexyl-1,4-diazabutadiene) was synthesized and structurally characterized by single crystal X-ray diffraction and VT H-1 NMR spectroscopy. The performances of this complex in atom transfer radical polymerization (ATRP) of styrene have been studied and related to the molecular structure.File in questo prodotto:
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