α,α-Diaryl-L-prolinols were disclosed to promote the desymmetrization of meso-N-acylaziridines with benzenethiols to afford the products in good yields and moderate enantioselectivities (up to 61% ee), which can be greatly improved to 90% ee after a single recrystallization.
Desymmetrization of meso-N-Acylaziridines with benzenthiols Promoted by a,a-Diaryl-L-Prolinols
LATTANZI, Alessandra;DELLA SALA, Giorgio
2009
Abstract
α,α-Diaryl-L-prolinols were disclosed to promote the desymmetrization of meso-N-acylaziridines with benzenethiols to afford the products in good yields and moderate enantioselectivities (up to 61% ee), which can be greatly improved to 90% ee after a single recrystallization.File in questo prodotto:
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