Chiral homoallylic alcohols are easily accessible by asymmetric allylation of aldehydes with allyl trichlorosilane in the presence of catalytic amounts of a chiral tetradentate bis-sulfoxide, as organocatalyst, whose synthesis is reported.

A catalytic asymmetric allylation of aldehydes with allyl trichlorosilane activated by a chiral tetradentate bis-sulfoxide

MASSA, Antonio;ACOCELLA, MARIA ROSARIA;DE SIO, VINCENZO;VILLANO, Rosaria;SCETTRI, Arrigo
2009-01-01

Abstract

Chiral homoallylic alcohols are easily accessible by asymmetric allylation of aldehydes with allyl trichlorosilane in the presence of catalytic amounts of a chiral tetradentate bis-sulfoxide, as organocatalyst, whose synthesis is reported.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11386/2293525
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