The Ti(IV)/(R)-BINOL catalyzed aldol condensation of trimethylsilyloxydiene, deriving from 2,2,6-trimethyl-4H-[1,3]-dioxin-4-one, is shown to proceed through an auto-inductive process with amplification of enantiomeric excess (e.e.).
Asymmetric auto-inductive aldol reaction by self-assembly of chiral ligands
DE ROSA, Margherita;ACOCELLA, MARIA ROSARIA;SORIENTE, Annunziata;SCETTRI, Arrigo
2001
Abstract
The Ti(IV)/(R)-BINOL catalyzed aldol condensation of trimethylsilyloxydiene, deriving from 2,2,6-trimethyl-4H-[1,3]-dioxin-4-one, is shown to proceed through an auto-inductive process with amplification of enantiomeric excess (e.e.).File in questo prodotto:
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