E- and Z-Enediones are easily accessible by controlled oxidation of 2,5-disubstituted furans with Mo(CO)6/cumyl hydroperoxide system. The use of t-butyl hydroperoxide, as oxygen donor, leads to the formation of 2H-pyran-3(6H)-one derivatives.
Mo(CO)6-Catalyzed oxidation of furan derivatives to E- and Z-enediones by cumyl hydroperoxide
MASSA, Antonio;ACOCELLA, MARIA ROSARIA;DE ROSA, Margherita;SORIENTE, Annunziata;SCETTRI, Arrigo
2003
Abstract
E- and Z-Enediones are easily accessible by controlled oxidation of 2,5-disubstituted furans with Mo(CO)6/cumyl hydroperoxide system. The use of t-butyl hydroperoxide, as oxygen donor, leads to the formation of 2H-pyran-3(6H)-one derivatives.File in questo prodotto:
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