Propene reacts smoothly with the alkene polymerization catalyst [Zr(CH2Ph)3{(eta6-PhCH2)B(C6F5)3)] 1 to give initially the single-insertion adduct [Zr(eta(n)-CH2Ph)2(CH2CHMeCH2Ph)]+[B(CH2Ph)(C6F5)3]- 2, which has been isolated and characterized.
Isolation of A Single-insertion Intermediate In the Catalytic Polymerization of Propene By A Cationic Tris(hydrocarbyl) Zirconium Complex
PELLECCHIA, Claudio;GRASSI, Alfonso;ZAMBELLI, Adolfo
1993-01-01
Abstract
Propene reacts smoothly with the alkene polymerization catalyst [Zr(CH2Ph)3{(eta6-PhCH2)B(C6F5)3)] 1 to give initially the single-insertion adduct [Zr(eta(n)-CH2Ph)2(CH2CHMeCH2Ph)]+[B(CH2Ph)(C6F5)3]- 2, which has been isolated and characterized.File in questo prodotto:
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