Polymerizations of (R,S)-3,7-dimethyl-1-octene in the presence of heterogeneous or homogeneous isotactic specific catalysts give very similar products with a homopolymeric isotactic structure. The insertion of (R,S)-3,7-dimethyl-1-octene into the metal-CH3 bend (both heterogeneous and homogeneous catalysts) is highly stereospecific and stereoselective.

C-13-enriched end groups of poly(3,7-dimethyl-1-octene) prepared in the presence of isotactic specific catalysts

LONGO, Pasquale;OLIVA, Leone
1997

Abstract

Polymerizations of (R,S)-3,7-dimethyl-1-octene in the presence of heterogeneous or homogeneous isotactic specific catalysts give very similar products with a homopolymeric isotactic structure. The insertion of (R,S)-3,7-dimethyl-1-octene into the metal-CH3 bend (both heterogeneous and homogeneous catalysts) is highly stereospecific and stereoselective.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11386/3133878
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