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EnglishThe first calixarenes bearing chiral glycidyl groups at the lower rim have been obtained by treatment of p-tert-butylcalix[4]arene (1a) and p-tert-butylcalix[6] with (1b) with glycidyl tosylate or 3-nitrobenzenesulfonate in the presence of a base. Their structure was established as syn-1,3-diglycidyl calix[4]arene 2, tetraglycidyl calix[4]arene 3 (partial cone, 1,2-alternate and 1,3-alternate confonners), and 1,2,4,5-tetraglycidyl calix[6]arene 4, respectively, by H-1 and C-13 NMR spectroscopy. Regio- and stereoselective epoxide ring-opening of 2 with amines led to chiral beta-aminoalcohols (5 and 6).
http://hdl.handle.net/11386/3136526| Titolo: | Synthesis of glycidyl calixarenes, versatile substrates for the preparation of chiral calixarene-based ligands |
| Autori interni: | NERI, Placido |
| Data di pubblicazione: | 1996 |
| Rivista: | TETRAHEDRON-ASYMMETRY |
| Abstract: | The first calixarenes bearing chiral glycidyl groups at the lower rim have been obtained by treatment of p-tert-butylcalix[4]arene (1a) and p-tert-butylcalix[6] with (1b) with glycidyl tosylate or 3-nitrobenzenesulfonate in the presence of a base. Their structure was established as syn-1,3-diglycidyl calix[4]arene 2, tetraglycidyl calix[4]arene 3 (partial cone, 1,2-alternate and 1,3-alternate confonners), and 1,2,4,5-tetraglycidyl calix[6]arene 4, respectively, by H-1 and C-13 NMR spectroscopy. Regio- and stereoselective epoxide ring-opening of 2 with amines led to chiral beta-aminoalcohols (5 and 6). |
| Handle: | http://hdl.handle.net/11386/3136526 |
| Appare nelle tipologie: | 1.1.2 Articolo su rivista con ISSN |
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