Palladium acetate reacts with the weak carbon. acid MeSCH(2)R (R = C(O)OEt) to give [Pd-3(mu-O(2)CMe)(3)(mu-MeSCHR)(3)] (1), characterized by X-ray crystallography. The MeSCHC(O)OEt(-) anion acts as a bidentate Ligand binding two palladium atoms via a (Me)SCH(R) bridge, in which the methine carbon. is chiral. Complex 1 is the first mixed-sphere palladium complex in which the solid-state nuclearity and structure of palladium acetate is retained.
Easy Metalation of the Substituted Dimethyl Sulfide Mesch(2)r (r=c(o)oet) By Palladium Acetate and Characterization of the Trinuclear Mixed-sphere [pd-3(mu-o(2)cme)(3)(mu-meschr)(3)] Complex
GRASSI, Alfonso;
1995
Abstract
Palladium acetate reacts with the weak carbon. acid MeSCH(2)R (R = C(O)OEt) to give [Pd-3(mu-O(2)CMe)(3)(mu-MeSCHR)(3)] (1), characterized by X-ray crystallography. The MeSCHC(O)OEt(-) anion acts as a bidentate Ligand binding two palladium atoms via a (Me)SCH(R) bridge, in which the methine carbon. is chiral. Complex 1 is the first mixed-sphere palladium complex in which the solid-state nuclearity and structure of palladium acetate is retained.File in questo prodotto:
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