Epoxidation of double bond was the main reaction performed by Zoophthora (Erynia) ovispora on methyl and ethyl alpha-campholenyl ketones 1 and 6. Apart from epoxides 2, 3, 7, and 8, some other products were isolated, with additional oxygen function in alpha-position to the double bond (9 and 10). The presence of the BAEYER-VILLIGER reaction product (4) and diketone 11 is also postulated.
Microbial Transformation of Isoprenoid Systems By Means of Zoophthora (erynia) Ovispora (nowakowski) Batko
GRASSI, Alfonso
1993-01-01
Abstract
Epoxidation of double bond was the main reaction performed by Zoophthora (Erynia) ovispora on methyl and ethyl alpha-campholenyl ketones 1 and 6. Apart from epoxides 2, 3, 7, and 8, some other products were isolated, with additional oxygen function in alpha-position to the double bond (9 and 10). The presence of the BAEYER-VILLIGER reaction product (4) and diketone 11 is also postulated.File in questo prodotto:
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