Chiral sulfoxides are accessible with very satisfactory enantiomeric excesses through a modified Sharpless procedure, based on the employment of furylhydroperoxides. Racemic hydroperoxides are found to undergo a kinetic resolution in the course of the asymmetric oxidation.
Asymmetric oxidation with furylhydroperoxides
SCETTRI, Arrigo;LATTANZI, Alessandra
1996
Abstract
Chiral sulfoxides are accessible with very satisfactory enantiomeric excesses through a modified Sharpless procedure, based on the employment of furylhydroperoxides. Racemic hydroperoxides are found to undergo a kinetic resolution in the course of the asymmetric oxidation.File in questo prodotto:
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