Single-crystal X-ray analysis of the ionic complex [(C5Me5)Zr(CH2Ph)2]+[B(CH2Ph)(C6F5)3]- shows that no cation-anion bonding interactions exist, resulting in remarkable structural features in the highly electrophilic ''naked'' cation, including an unprecedented eta7-benzyl coordination.
A Novel Eta-7 Coordination Mode of A Benzyl Ligand In A Cationic Zirconium Complex
PELLECCHIA, Claudio;PAPPALARDO, Daniela;PELUSO, Andrea
1994-01-01
Abstract
Single-crystal X-ray analysis of the ionic complex [(C5Me5)Zr(CH2Ph)2]+[B(CH2Ph)(C6F5)3]- shows that no cation-anion bonding interactions exist, resulting in remarkable structural features in the highly electrophilic ''naked'' cation, including an unprecedented eta7-benzyl coordination.File in questo prodotto:
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