A four-step synthesis of sterically demanding (R)-phenanthren-9-yl-[(S)-pyrrolidin- 2-yl]methanol has been easily accomplished starting fromL-proline in high diastereoselectivity. These compounds are potentially useful ligands in metal-catalyzed reactions and organocatalysts.
Diastereoselective Synthesis of (R)- Phenanthrenyl-9yl-[(S)-pyrrolidin-2yl)] Methanol
RUSSO, ALESSIO;FUOCO, TIZIANA;LATTANZI, Alessandra
2013
Abstract
A four-step synthesis of sterically demanding (R)-phenanthren-9-yl-[(S)-pyrrolidin- 2-yl]methanol has been easily accomplished starting fromL-proline in high diastereoselectivity. These compounds are potentially useful ligands in metal-catalyzed reactions and organocatalysts.File in questo prodotto:
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