A four-step synthesis of sterically demanding (R)-phenanthren-9-yl-[(S)-pyrrolidin- 2-yl]methanol has been easily accomplished starting fromL-proline in high diastereoselectivity. These compounds are potentially useful ligands in metal-catalyzed reactions and organocatalysts.

Diastereoselective Synthesis of (R)- Phenanthrenyl-9yl-[(S)-pyrrolidin-2yl)] Methanol

RUSSO, ALESSIO;FUOCO, TIZIANA;LATTANZI, Alessandra
2013

Abstract

A four-step synthesis of sterically demanding (R)-phenanthren-9-yl-[(S)-pyrrolidin- 2-yl]methanol has been easily accomplished starting fromL-proline in high diastereoselectivity. These compounds are potentially useful ligands in metal-catalyzed reactions and organocatalysts.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11386/3976212
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