Partner preferences in pseudorotaxane formation were exploited to establish an integrative self-sorting system able to discriminate simultaneously at the sequence and stereochemical level (see picture). It was found that calix[6]arenes were threaded selectively with a preferred orientation onto bisammonium axles, even when the structural differences between the possible building blocks were small and located remote from the binding sites
Pseudorotaxanes with Self-Sorted Sequence and Stereochemical Orientation
TALOTTA, CARMENMembro del Collaboration Group
;GAETA, CARMINEMembro del Collaboration Group
;NERI, Placido
Membro del Collaboration Group
;
2013-01-01
Abstract
Partner preferences in pseudorotaxane formation were exploited to establish an integrative self-sorting system able to discriminate simultaneously at the sequence and stereochemical level (see picture). It was found that calix[6]arenes were threaded selectively with a preferred orientation onto bisammonium axles, even when the structural differences between the possible building blocks were small and located remote from the binding sitesFile in questo prodotto:
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