The first example of an oriented handcuff rotaxane has been obtained by through-the-annulus threading of a double-calix[6]arene system with a bis-ammonium axle. The relative orientation of the two calix-wheels can be predefined by exploiting the “endo-alkyl rule” which controls the directionality of the threading of alkylbenzylammonium axles with calixarene macrocycles.

An Oriented Handcuff Rotaxane

CIAO, ROBERTA;TALOTTA, CARMEN;GAETA, CARMINE;MARGARUCCI, LUIGI;CASAPULLO, Agostino;NERI, Placido
2013

Abstract

The first example of an oriented handcuff rotaxane has been obtained by through-the-annulus threading of a double-calix[6]arene system with a bis-ammonium axle. The relative orientation of the two calix-wheels can be predefined by exploiting the “endo-alkyl rule” which controls the directionality of the threading of alkylbenzylammonium axles with calixarene macrocycles.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11386/4204861
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