Aluminum complexes of enantiomerically pure aminomethylpyrrolidine-based salalen ligands and their application in the stereoselective polymerization of lactide are described. Poly(lactic acid) featuring the new gradient isotactic multiblock microstructure was synthesized by isoselective catalysts, which operate by a combination of enantiomorphic-site and chain-end control mechanisms.
Gradient Isotactic Multiblock Polylactides from Aluminum Complexes of Chiral Salalen Ligands
PILONE, ALESSIA;MAZZEO, Mina;LAMBERTI, Marina
2014-01-01
Abstract
Aluminum complexes of enantiomerically pure aminomethylpyrrolidine-based salalen ligands and their application in the stereoselective polymerization of lactide are described. Poly(lactic acid) featuring the new gradient isotactic multiblock microstructure was synthesized by isoselective catalysts, which operate by a combination of enantiomorphic-site and chain-end control mechanisms.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
