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EnglishIt is here demonstrated that the p-bromodienone route, previously reported for calix[4]arenes, is also effective for the functionalization of the calix[6]arene macrocycle. Thus, alcoholic O-nucleophiles can be introduced at the calix[6]arene exo rim. In addition, the reaction of a calix[6]arene p-bromodienone derivative with an actived aromatic substrate, such as resorcinol, led to the first example of a meta-functionalized, inherently chiral calix[6]arene derivative
| Titolo: | Nucleophilic Functionalization of the Calix[6]arene Para- and Meta-Position via p‑Bromodienone Route |
| Autori: | |
| Data di pubblicazione: | 2015 |
| Rivista: | |
| Abstract: | It is here demonstrated that the p-bromodienone route, previously reported for calix[4]arenes, is also effective for the functionalization of the calix[6]arene macrocycle. Thus, alcoholic O-nucleophiles can be introduced at the calix[6]arene exo rim. In addition, the reaction of a calix[6]arene p-bromodienone derivative with an actived aromatic substrate, such as resorcinol, led to the first example of a meta-functionalized, inherently chiral calix[6]arene derivative |
| Handle: | http://hdl.handle.net/11386/4648822 |
| Appare nelle tipologie: | 1.1.2 Articolo su rivista con ISSN |
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