An example of calixarene-mediated catalysis under “on-water” conditions is here reported. In the presence of thioureido-calixarenes a rate acceleration for the Vinylogous Mukaiyama Aldol Reaction (VMAR) was observed, under on-water conditions. The ability of the calixarene catalyst to accelerate the VMAR under on-water conditions is closely related to its hydrophobicity and to its recognition abilities toward the substrate

Exploiting the hydrophobicity of calixarene macrocycles for catalysis under “on-water” conditions

DE ROSA, Margherita;LA MANNA, PELLEGRINO;SORIENTE, Annunziata;GAETA, CARMINE;TALOTTA, CARMEN;NERI, Placido
2016-01-01

Abstract

An example of calixarene-mediated catalysis under “on-water” conditions is here reported. In the presence of thioureido-calixarenes a rate acceleration for the Vinylogous Mukaiyama Aldol Reaction (VMAR) was observed, under on-water conditions. The ability of the calixarene catalyst to accelerate the VMAR under on-water conditions is closely related to its hydrophobicity and to its recognition abilities toward the substrate
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11386/4673686
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