An example of calixarene-mediated catalysis under “on-water” conditions is here reported. In the presence of thioureido-calixarenes a rate acceleration for the Vinylogous Mukaiyama Aldol Reaction (VMAR) was observed, under on-water conditions. The ability of the calixarene catalyst to accelerate the VMAR under on-water conditions is closely related to its hydrophobicity and to its recognition abilities toward the substrate
Exploiting the hydrophobicity of calixarene macrocycles for catalysis under “on-water” conditions
DE ROSA, Margherita;LA MANNA, PELLEGRINO;SORIENTE, Annunziata;GAETA, CARMINE;TALOTTA, CARMEN;NERI, Placido
2016-01-01
Abstract
An example of calixarene-mediated catalysis under “on-water” conditions is here reported. In the presence of thioureido-calixarenes a rate acceleration for the Vinylogous Mukaiyama Aldol Reaction (VMAR) was observed, under on-water conditions. The ability of the calixarene catalyst to accelerate the VMAR under on-water conditions is closely related to its hydrophobicity and to its recognition abilities toward the substrateFile in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
RSC Adv 2016_Manuscript _marked.pdf
non disponibili
Tipologia:
Documento in Post-print (versione successiva alla peer review e accettata per la pubblicazione)
Licenza:
Creative commons
Dimensione
600.51 kB
Formato
Adobe PDF
|
600.51 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
