The decomposition of formic acid into H-2 and CO2 was successfully performed using a ruthenium hydride catalyst, without any concomitant CO evolution. The reaction mechanism is investigated by means of density functional theory calculations (DFT). The generated H-2 was further exploited in a fuel cell to produce electricity. The catalytic hydrogenation of conjugated olefins, using this dihydrogen generation procedure, is also reported. (C) 2017 Elsevier B.V. All rights reserved.
Ruthenium-catalysed decomposition of formic acid: Fuel cell and catalytic applications
Cavallo, Luigi;
2017-01-01
Abstract
The decomposition of formic acid into H-2 and CO2 was successfully performed using a ruthenium hydride catalyst, without any concomitant CO evolution. The reaction mechanism is investigated by means of density functional theory calculations (DFT). The generated H-2 was further exploited in a fuel cell to produce electricity. The catalytic hydrogenation of conjugated olefins, using this dihydrogen generation procedure, is also reported. (C) 2017 Elsevier B.V. All rights reserved.File in questo prodotto:
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