We propose a model for MgCl2-supported Ziegler-Natta catalysts, which is capable to reconcile the discrepancies emerging in the last 20 years, in which attempts have been made to rationalize experimental data by molecular models. We show that step defects on the thermodynamically more stable (104) facet of MgCl2 can lead to sites for strong TiCl4 adsorption. The corresponding Ti-active site is stereoeselective, and its stereoselectivity can be enhanced by coordination of Al-alkyls or Lewis bases in the close proximity. The surface energy of the step defected (104) MgCl2 facet is dearly lower than that of the well accepted (110) facet.
Toward a Unified Model Explaining Heterogeneous Ziegler-Natta Catalysis
Cavallo, Luigi
2015
Abstract
We propose a model for MgCl2-supported Ziegler-Natta catalysts, which is capable to reconcile the discrepancies emerging in the last 20 years, in which attempts have been made to rationalize experimental data by molecular models. We show that step defects on the thermodynamically more stable (104) facet of MgCl2 can lead to sites for strong TiCl4 adsorption. The corresponding Ti-active site is stereoeselective, and its stereoselectivity can be enhanced by coordination of Al-alkyls or Lewis bases in the close proximity. The surface energy of the step defected (104) MgCl2 facet is dearly lower than that of the well accepted (110) facet.File in questo prodotto:
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