Since the report of the stereospecific polymerization of styrene dated 2003, metal complexes bearing [OSSO]-bisphenolate ligands have been successfully applied in different branches of homogeneous catalysis, de facto building a new research field. This review will focus on polymerization reactions promoted by these complexes, starting with those involving “traditional” monomers (such as fossil-derived olefins) up to more recent and green applications, like polymerization of terpenes or utilization of CO2 as a green building block.

[OSSO]-bisphenolate metal complexes: A powerful and versatile tool in polymerization catalysis

Paradiso V.;Capaccio V.;Lamparelli D. H.;Capacchione C.
2021-01-01

Abstract

Since the report of the stereospecific polymerization of styrene dated 2003, metal complexes bearing [OSSO]-bisphenolate ligands have been successfully applied in different branches of homogeneous catalysis, de facto building a new research field. This review will focus on polymerization reactions promoted by these complexes, starting with those involving “traditional” monomers (such as fossil-derived olefins) up to more recent and green applications, like polymerization of terpenes or utilization of CO2 as a green building block.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11386/4754526
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