Since the report of the stereospecific polymerization of styrene dated 2003, metal complexes bearing [OSSO]-bisphenolate ligands have been successfully applied in different branches of homogeneous catalysis, de facto building a new research field. This review will focus on polymerization reactions promoted by these complexes, starting with those involving “traditional” monomers (such as fossil-derived olefins) up to more recent and green applications, like polymerization of terpenes or utilization of CO2 as a green building block.
[OSSO]-bisphenolate metal complexes: A powerful and versatile tool in polymerization catalysis
Paradiso V.;Capaccio V.;Lamparelli D. H.;Capacchione C.
2021-01-01
Abstract
Since the report of the stereospecific polymerization of styrene dated 2003, metal complexes bearing [OSSO]-bisphenolate ligands have been successfully applied in different branches of homogeneous catalysis, de facto building a new research field. This review will focus on polymerization reactions promoted by these complexes, starting with those involving “traditional” monomers (such as fossil-derived olefins) up to more recent and green applications, like polymerization of terpenes or utilization of CO2 as a green building block.File in questo prodotto:
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