The tetradentate dianionic {ONNO}-type salanol ligands featuring phenolate and alcoholate arms and a chiral-bipyrrolidine core are introduced. The diastereoselectively-formed {ONNO}-Al-OBn complexes catalyze the ring-opening polymerization of rac-lactide and meso-lactide by either the dual stereocontrol or the chain-end stereocontrol mechanisms to give PLAs of all possible tacticities. This journal is
Aluminium complexes of salanol ligands: coordination chemistry and stereoselective lactide polymerization
Venditto V.
;Kol M.
2020-01-01
Abstract
The tetradentate dianionic {ONNO}-type salanol ligands featuring phenolate and alcoholate arms and a chiral-bipyrrolidine core are introduced. The diastereoselectively-formed {ONNO}-Al-OBn complexes catalyze the ring-opening polymerization of rac-lactide and meso-lactide by either the dual stereocontrol or the chain-end stereocontrol mechanisms to give PLAs of all possible tacticities. This journal isFile in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
