The current work introduced a convenient single-phase hydrothermal protocol to fabricate MnO2 nanorods (MnO2 NRs). Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Energy-dispersive X-ray spectroscopy (EDX) and field-emission scanning electron microscopy (FE-SEM) were used to determine the characteristics of MnO2 NR. Then, ionic liquid (IL) and MnO2 NRs were utilized to modify a carbon paste electrode (CPE) surface (MnO2NRIL/CPE) to voltammetrically sense the sulfanilamide (SAA). An enhanced voltammetric sensitivity was found for the as-developed modified electrode toward SAA when compared with a bare electrode. The optimization experiments were designed to achieve the best analytical behavior of the SAA sensor. Differential pulse voltammetry (DPV) in the optimized circumstances portrayed a linear dependence on various SAA levels (between 0.07 and 100.0 μM), possessing a narrow detection limit (0.01 μM). The ability of the modified electrode to be used in sensor applications was verified in the determination of SAA present in the actual urine and water specimens, with impressive recovery outcomes.

Application of MnO2 Nanorod–Ionic Liquid Modified Carbon Paste Electrode for the Voltammetric Determination of Sulfanilamide

Di Bartolomeo, Antonio Di
Writing – Review & Editing
2022

Abstract

The current work introduced a convenient single-phase hydrothermal protocol to fabricate MnO2 nanorods (MnO2 NRs). Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Energy-dispersive X-ray spectroscopy (EDX) and field-emission scanning electron microscopy (FE-SEM) were used to determine the characteristics of MnO2 NR. Then, ionic liquid (IL) and MnO2 NRs were utilized to modify a carbon paste electrode (CPE) surface (MnO2NRIL/CPE) to voltammetrically sense the sulfanilamide (SAA). An enhanced voltammetric sensitivity was found for the as-developed modified electrode toward SAA when compared with a bare electrode. The optimization experiments were designed to achieve the best analytical behavior of the SAA sensor. Differential pulse voltammetry (DPV) in the optimized circumstances portrayed a linear dependence on various SAA levels (between 0.07 and 100.0 μM), possessing a narrow detection limit (0.01 μM). The ability of the modified electrode to be used in sensor applications was verified in the determination of SAA present in the actual urine and water specimens, with impressive recovery outcomes.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11386/4782209
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