Borane complexes have long been recognized as efficient reducing agents. Among them, amine–borane complexes display a broad range of stability and reactivity, making them attractive for both laboratory and industrial applications. In this contribution, we report the reduction properties of a thermally stable macrocyclic triazole–borane complex (1) toward carbonyl and imine functional groups. The observed selectivity was investigated using theoretical calculation.
Chemoselective Aldehyde and Imine Reduction by a Macrocyclic Triazole–Borane Complex Triggered by a Non‐innocent Proton–Hydride Interaction
Di Marino, LucaMembro del Collaboration Group
;Brotons Rufes, ArturMembro del Collaboration Group
;Schettini, RosariaMembro del Collaboration Group
;Della Sala, GiorgioMembro del Collaboration Group
;De Riccardis, FrancescoMembro del Collaboration Group
;Costabile, Chiara
Conceptualization
;Izzo, Irene
Conceptualization
2026
Abstract
Borane complexes have long been recognized as efficient reducing agents. Among them, amine–borane complexes display a broad range of stability and reactivity, making them attractive for both laboratory and industrial applications. In this contribution, we report the reduction properties of a thermally stable macrocyclic triazole–borane complex (1) toward carbonyl and imine functional groups. The observed selectivity was investigated using theoretical calculation.File in questo prodotto:
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