This study introduces advanced epoxy formulations incorporating carbon-based nanofillers, carbon nanotubes, nanofibers, and functionalized graphene. The epoxy matrix was optimized to lower moisture absorption and enhance multifunctional properties. A non-stoichiometric epoxy/hardener ratio reduced equilibrium water concentration (Ceq) by up to 30% compared to unmodified epoxy, achieved by minimizing polar groups responsible for water bonding. These improvements benefit the aerospace, marine, and wind energy sectors. All nanofillers form a secondary phase with reduced glass transition temperature (Tg), but functionalized graphene performs best. Its self-assembled sheet architectures trap resin, limit water interaction, and create conductive pathways, improving strength, reducing moisture uptake, and achieving a low electrical percolation threshold (EPT).
Smart Design of an Innovative Generation of Structural Resins Loaded with Carbon Nanostructured Forms †
Guadagno L.;Raimondo M.;Aliberti F.;Longo R.;Vertuccio L.
2026
Abstract
This study introduces advanced epoxy formulations incorporating carbon-based nanofillers, carbon nanotubes, nanofibers, and functionalized graphene. The epoxy matrix was optimized to lower moisture absorption and enhance multifunctional properties. A non-stoichiometric epoxy/hardener ratio reduced equilibrium water concentration (Ceq) by up to 30% compared to unmodified epoxy, achieved by minimizing polar groups responsible for water bonding. These improvements benefit the aerospace, marine, and wind energy sectors. All nanofillers form a secondary phase with reduced glass transition temperature (Tg), but functionalized graphene performs best. Its self-assembled sheet architectures trap resin, limit water interaction, and create conductive pathways, improving strength, reducing moisture uptake, and achieving a low electrical percolation threshold (EPT).I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
