The investigation of the solid state assembly of propargyl substituted hexa- and octacyclic peptoids highlights the effect of ring size in determining the packing arrangement of the macrocycles. A layered arrangement is obtained in the case of the hexacyclic peptoid 1 and a tubular arrangement in the case of the octacyclic peptoid 2. Guest molecules either intercalate between the layers as in 1 or are located within the peptoid nanotubes as in 2.
Ring size effect on the solid state assembly of propargyl substituted hexa- and octacyclic peptoids
TEDESCO, Consiglia
;MELI, ALESSANDRA;MACEDI, ELEONORA;IULIANO, VERONICA;DE RICCARDIS, Francesco;IZZO, Irene
2016
Abstract
The investigation of the solid state assembly of propargyl substituted hexa- and octacyclic peptoids highlights the effect of ring size in determining the packing arrangement of the macrocycles. A layered arrangement is obtained in the case of the hexacyclic peptoid 1 and a tubular arrangement in the case of the octacyclic peptoid 2. Guest molecules either intercalate between the layers as in 1 or are located within the peptoid nanotubes as in 2.File in questo prodotto:
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