The investigation of the solid state assembly of propargyl substituted hexa- and octacyclic peptoids highlights the effect of ring size in determining the packing arrangement of the macrocycles. A layered arrangement is obtained in the case of the hexacyclic peptoid 1 and a tubular arrangement in the case of the octacyclic peptoid 2. Guest molecules either intercalate between the layers as in 1 or are located within the peptoid nanotubes as in 2.

Ring size effect on the solid state assembly of propargyl substituted hexa- and octacyclic peptoids

TEDESCO, Consiglia
;
MELI, ALESSANDRA;MACEDI, ELEONORA;IULIANO, VERONICA;DE RICCARDIS, Francesco;IZZO, Irene
2016-01-01

Abstract

The investigation of the solid state assembly of propargyl substituted hexa- and octacyclic peptoids highlights the effect of ring size in determining the packing arrangement of the macrocycles. A layered arrangement is obtained in the case of the hexacyclic peptoid 1 and a tubular arrangement in the case of the octacyclic peptoid 2. Guest molecules either intercalate between the layers as in 1 or are located within the peptoid nanotubes as in 2.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11386/4676930
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