Oxidized carbon black efficiently catalyzed addition of amines to 1,3-dicarbonyl compounds under solvent-free conditions at room temperature. This methodology is eco-friendly and cheap, with a very easy work up and the possibility to recover and recycle the catalyst. Finally, the elaborated methodology can be conveniently exploited for the synthesis of 1,5-benzodiazepine.

Oxidized Carbon Black as Catalysts for the Enamine Formation in Solvent-Free Conditions: A Green Strategy to Build the Benzodiazepine Scaffold

Villano, Rosaria;Acocella, Maria Rosaria
;
Guerra, Gaetano
2017

Abstract

Oxidized carbon black efficiently catalyzed addition of amines to 1,3-dicarbonyl compounds under solvent-free conditions at room temperature. This methodology is eco-friendly and cheap, with a very easy work up and the possibility to recover and recycle the catalyst. Finally, the elaborated methodology can be conveniently exploited for the synthesis of 1,5-benzodiazepine.
2017
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11386/4704339
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