Control Oriented Modeling of SCR Systems for Automotive Application

In the last decades, NOxemissions legislations for Diesel engines are becoming more stringent than ever before and the selective catalytic reduction (SCR) is considered as the most suitable technology to comply with the upcoming constraints. Model-based control strategies are promising to meet the dual objective of maximizing NOxreduction and minimizing NH3slip in urea-selective catalytic reduction. In this paper, a control oriented model of a Cu-zeolite urea-SCR system for automotive diesel engines is presented. The model is derived from a quasi-dimensional four-state model of the urea-SCR plant. To make it suitable for the real-time urea-SCR management, a reduced order one-state model has been developed, with the aim of capturing the essential behavior of the system with a low computational burden. Particularly, the model allows estimating the NH3slip that is fundamental not only to minimize urea consumption but also to reduce this unregulated emission. Parameters identification and model validation have been performed vs. simulation data achieved by a commercial code of the SCR system, based on the four-state quasi-dimensional modeling approach. The accuracy of the reduced-order model is demonstrated by comparing NO, NO2and NH3concentrations with those simulated by the more complex reference model. It is observed that the one state model allows estimating the SCR behavior with good accuracy and low computational demand thus being suitable for real-time application.