The macrocyclization of 2,6-dialkoxynaphthalene monomers toprism[5]arenes is thermodynamically templated by DABCO cations. In this study,we demonstrate that a greater template affinity for prism[5]arene improves themacrocyclization yield. By using novel templating cations, the yield of alkoxy-prism[5]arenes increases significantly compared with those of previously reportedprocedures, while the purification process becomes easier and faster.
Thermodynamically Templated Macrocyclizations: Enhancing the Synthesis of Prism[5]arenes with Tailor-Made Guests
Del Regno, RoccoMethodology
;Palmieri, AnnaMethodology
;Della Sala, PaoloInvestigation
;Talotta, CarmenVisualization
;De Rosa, MargheritaWriting – Original Draft Preparation
;Campanile, GiuseppaFormal Analysis
;Argenio, ClaudiaData Curation
;Gaeta, Carmine
Supervision
2024-01-01
Abstract
The macrocyclization of 2,6-dialkoxynaphthalene monomers toprism[5]arenes is thermodynamically templated by DABCO cations. In this study,we demonstrate that a greater template affinity for prism[5]arene improves themacrocyclization yield. By using novel templating cations, the yield of alkoxy-prism[5]arenes increases significantly compared with those of previously reportedprocedures, while the purification process becomes easier and faster.File in questo prodotto:
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MS_Tailor Made Template for Prismarene_Final.pdf
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